FAQFAQ   SearchSearch   MemberlistMemberlist   UsergroupsUsergroups   RegisterRegister 
 ProfileProfile   PreferencesPreferences   Log in to check your private messagesLog in to check your private messages   Log inLog in 
Forum index » Science and Technology » Chem
water softening question
Post new topic   Reply to topic Page 1 of 1 [7 Posts] View previous topic :: View next topic
Author Message
sprsso
science forum beginner


Joined: 17 May 2005
Posts: 5

PostPosted: Tue May 17, 2005 6:06 pm    Post subject: water softening question Reply with quote

Hey,
I hope I'm in the right place.
I have a dilemna concerning water hardness testing. I work for a
company that supplies espresso equipment to several large restaurant
chains nationally.
Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.
It is unlikely that the softening cartridge could have been changed
without the knowledge of management. Tests were conducted with Hach
hardness test kits.
A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping". I am
not familiar with these points, but as our resident espresso expert, it
has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?
How much does the quality of the softening resin impact the
effectiveness of the softener, and could it occlude readings?
Anyone familiar with the term dumping?
If I am not asking in the right place, or the questions are too
amateurish for consideration, I apologize.
If there is someplace where these questions would be more appropriate,
I would appreciate being pointed to it, or any refence locations that
might help.
Thanks in advance....al
Back to top
Uncle Al
science forum Guru


Joined: 24 Mar 2005
Posts: 1226

PostPosted: Tue May 17, 2005 6:44 pm    Post subject: Re: water softening question Reply with quote

sprsso wrote:
Quote:

Hey,
I hope I'm in the right place.
I have a dilemna concerning water hardness testing. I work for a
company that supplies espresso equipment to several large restaurant
chains nationally.
Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.
It is unlikely that the softening cartridge could have been changed
without the knowledge of management. Tests were conducted with Hach
hardness test kits.
A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping". I am
not familiar with these points, but as our resident espresso expert, it
has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?
How much does the quality of the softening resin impact the
effectiveness of the softener, and could it occlude readings?
Anyone familiar with the term dumping?
If I am not asking in the right place, or the questions are too
amateurish for consideration, I apologize.
If there is someplace where these questions would be more appropriate,
I would appreciate being pointed to it, or any refence locations that
might help.
Thanks in advance....al

You might find it interesting to bring along a Geiger counter, too.
Rumor has it that nuclear powerplant polishing resins are dumped on
the consumer market for water softeners, bringing along a "harmless"
loading of crickets. It might be instructive to run the detector hard
by the resin vessel and take a listen to its effluent - especially the
first draw of the morning less the preceding dead volume.

If there is wall board, survey that. Phosphate fertilizer byproduct
waste is gypsum. The superphosphate product may be assayed for
radiation, but the wall board-recyclable gypsum is not. Uranium
segregates with calcium after it is freed from phosphate.


--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/qz.pdf
Back to top
sprsso
science forum beginner


Joined: 17 May 2005
Posts: 5

PostPosted: Tue May 17, 2005 9:03 pm    Post subject: Re: water softening question Reply with quote

f*** you, b***h. At one point years ago you were helpful and I gave you
credit as providing valuable info that actually had some insight. Now
you are apparently relegated to ascerbic, nonviable a*****le with
nothing valid to offer. I'll bet you thought that was funny.
I welcome responses from people who actually know what they're talking
about, not those that disguise their ignorance as what they perceive to
be comedy. Don't waste my bandwidth with your lame attempt to be
humorous.And stop doing that. You'll go blind....mom
Back to top
ian.kirker@gmail.com
science forum beginner


Joined: 17 May 2005
Posts: 4

PostPosted: Tue May 17, 2005 9:32 pm    Post subject: Re: water softening question Reply with quote

Before I say anything, I should mention that I'm no expert in water
softeners.

However, as I understand it, water softener resin is, essentially, an
ion exchange resin, that exchanges calcium or magnesium for sodium or
hydrogen ions, and carbonate or other negatively charged ions for
chloride or hydroxide, depending on the type (brine regenerated or
acid/alkali regenerated).

Now, different ions will have different affinities for the particular
resin, and so, over time, the more strongly bonding one will become
predominant as it may displace more weakly bonding ions. If most of the
sites are occupied with bound calcium and magnesium ions, then an input
of more ions may result in a mass displacement of the less favoured ion
(calcium, I think), and so a higher concentration of that ion than you
started with. This is what I have been led to understand is meant by
"dumping".

I don't know how the quality of the resin affects this, unfortunately.

(Hope this helps a little.)
Back to top
Martin Brown
science forum addict


Joined: 12 May 2005
Posts: 82

PostPosted: Wed May 18, 2005 6:12 am    Post subject: Re: water softening question Reply with quote

sprsso wrote:
Quote:
Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.

Next time it happens have the engineer take a sample of the dodgy
"impure" water in a suitable ultra-trace sealed vial. Then submit it for
a semiquantitative lab analysis (eg by ICP) for the obvious hard water
components to find out what is actually there. Plenty of labs can
analyse clean drinking water relatively cheaply.

Quote:
A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping".

I am inclined to the view that the reading may well have been real at
the time it was made. The question is how long did it occur for and can
your espresso kit tolerate it happening occasionally.

Quote:
has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?

Why do you suppose the reading was false?
(apart from the assurances of the filter manufacturer)

Try cross posting into sci.chem.analytical and you may pick up some more
tips specific to measurments on potable water.

Regards,
Martin Brown
Back to top
Ernie
science forum beginner


Joined: 18 May 2005
Posts: 16

PostPosted: Wed May 18, 2005 11:01 am    Post subject: Re: water softening question Reply with quote

"sprsso" <acritzer@cfl.rr.com> wrote in message
news:1116360370.292963.249450@o13g2000cwo.googlegroups.com...
Quote:
Hey,
I hope I'm in the right place.
I have a dilemna concerning water hardness testing. I work for a
company that supplies espresso equipment to several large restaurant
chains nationally.
Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.
It is unlikely that the softening cartridge could have been changed
without the knowledge of management. Tests were conducted with Hach
hardness test kits.
A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping". I am
not familiar with these points, but as our resident espresso expert, it
has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?
How much does the quality of the softening resin impact the
effectiveness of the softener, and could it occlude readings?
Anyone familiar with the term dumping?
If I am not asking in the right place, or the questions are too
amateurish for consideration, I apologize.
If there is someplace where these questions would be more appropriate,
I would appreciate being pointed to it, or any refence locations that
might help.
Thanks in advance....al


It seems to me that if the exchange resin is close to used up, and the
sample is taken at high water flow rates, some Mg, and Ca is likely to get
through. On the other hand, if the next sample is taken at very low water
flow rates, or the sample is water that has been sitting in the exchange
cartridge, that sample may be free of Ca & Mg.

The moral of the story is that samples should be taken at flow rates equal
to the fill rate to the espresso machine.

Ernie
Back to top
sprsso
science forum beginner


Joined: 17 May 2005
Posts: 5

PostPosted: Wed May 18, 2005 3:32 pm    Post subject: Re: water softening question Reply with quote

Thank you...al
Back to top
Google

Back to top
Display posts from previous:   
Post new topic   Reply to topic Page 1 of 1 [7 Posts] View previous topic :: View next topic
The time now is Fri Jan 09, 2009 9:36 pm | All times are GMT
Forum index » Science and Technology » Chem
Jump to:  

Similar Topics
Topic Author Forum Replies Last Post
No new posts Question about Life. socratus Probability 0 Sun Jan 06, 2008 10:01 pm
No new posts Probability Question dumont Probability 0 Mon Oct 23, 2006 3:38 pm
No new posts Question about exponention WingDragon@gmail.com Math 2 Fri Jul 21, 2006 8:13 am
No new posts question on solartron 1260 carrie_yao@hotmail.com Electrochem 0 Fri Jul 21, 2006 7:11 am
No new posts A Combinatorics/Graph Theory Question mathlover Undergraduate 1 Wed Jul 19, 2006 11:30 pm

Credit Cards | Car Finance | Capitial One Visa Information | Posicionamiento en buscadores | Credit Card
Copyright © 2004-2005 DeniX Solutions SRL
Other DeniX Solutions sites: Electronics forum |  Medicine forum |  Unix/Linux blog |  Unix/Linux documentation |  Unix/Linux forums


Powered by phpBB © 2001, 2005 phpBB Group
[ Time: 0.3223s ][ Queries: 16 (0.2070s) ][ GZIP on - Debug on ]