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sprsso science forum beginner
Joined: 17 May 2005
Posts: 5
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Posted: Tue May 17, 2005 6:06 pm Post subject:
water softening question
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Hey,
I hope I'm in the right place.
I have a dilemna concerning water hardness testing. I work for a
company that supplies espresso equipment to several large restaurant
chains nationally.
Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.
It is unlikely that the softening cartridge could have been changed
without the knowledge of management. Tests were conducted with Hach
hardness test kits.
A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping". I am
not familiar with these points, but as our resident espresso expert, it
has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?
How much does the quality of the softening resin impact the
effectiveness of the softener, and could it occlude readings?
Anyone familiar with the term dumping?
If I am not asking in the right place, or the questions are too
amateurish for consideration, I apologize.
If there is someplace where these questions would be more appropriate,
I would appreciate being pointed to it, or any refence locations that
might help.
Thanks in advance....al |
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Uncle Al science forum Guru
Joined: 24 Mar 2005
Posts: 1226
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Posted: Tue May 17, 2005 6:44 pm Post subject:
Re: water softening question
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sprsso wrote:
| Quote: |
Hey,
I hope I'm in the right place.
I have a dilemna concerning water hardness testing. I work for a
company that supplies espresso equipment to several large restaurant
chains nationally.
Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.
It is unlikely that the softening cartridge could have been changed
without the knowledge of management. Tests were conducted with Hach
hardness test kits.
A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping". I am
not familiar with these points, but as our resident espresso expert, it
has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?
How much does the quality of the softening resin impact the
effectiveness of the softener, and could it occlude readings?
Anyone familiar with the term dumping?
If I am not asking in the right place, or the questions are too
amateurish for consideration, I apologize.
If there is someplace where these questions would be more appropriate,
I would appreciate being pointed to it, or any refence locations that
might help.
Thanks in advance....al
|
You might find it interesting to bring along a Geiger counter, too.
Rumor has it that nuclear powerplant polishing resins are dumped on
the consumer market for water softeners, bringing along a "harmless"
loading of crickets. It might be instructive to run the detector hard
by the resin vessel and take a listen to its effluent - especially the
first draw of the morning less the preceding dead volume.
If there is wall board, survey that. Phosphate fertilizer byproduct
waste is gypsum. The superphosphate product may be assayed for
radiation, but the wall board-recyclable gypsum is not. Uranium
segregates with calcium after it is freed from phosphate.
--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/qz.pdf |
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sprsso science forum beginner
Joined: 17 May 2005
Posts: 5
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Posted: Tue May 17, 2005 9:03 pm Post subject:
Re: water softening question
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f*** you, b***h. At one point years ago you were helpful and I gave you
credit as providing valuable info that actually had some insight. Now
you are apparently relegated to ascerbic, nonviable a*****le with
nothing valid to offer. I'll bet you thought that was funny.
I welcome responses from people who actually know what they're talking
about, not those that disguise their ignorance as what they perceive to
be comedy. Don't waste my bandwidth with your lame attempt to be
humorous.And stop doing that. You'll go blind....mom |
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ian.kirker@gmail.com science forum beginner
Joined: 17 May 2005
Posts: 4
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Posted: Tue May 17, 2005 9:32 pm Post subject:
Re: water softening question
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Before I say anything, I should mention that I'm no expert in water
softeners.
However, as I understand it, water softener resin is, essentially, an
ion exchange resin, that exchanges calcium or magnesium for sodium or
hydrogen ions, and carbonate or other negatively charged ions for
chloride or hydroxide, depending on the type (brine regenerated or
acid/alkali regenerated).
Now, different ions will have different affinities for the particular
resin, and so, over time, the more strongly bonding one will become
predominant as it may displace more weakly bonding ions. If most of the
sites are occupied with bound calcium and magnesium ions, then an input
of more ions may result in a mass displacement of the less favoured ion
(calcium, I think), and so a higher concentration of that ion than you
started with. This is what I have been led to understand is meant by
"dumping".
I don't know how the quality of the resin affects this, unfortunately.
(Hope this helps a little.) |
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Martin Brown science forum addict
Joined: 12 May 2005
Posts: 82
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Posted: Wed May 18, 2005 6:12 am Post subject:
Re: water softening question
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sprsso wrote:
| Quote: | Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.
|
Next time it happens have the engineer take a sample of the dodgy
"impure" water in a suitable ultra-trace sealed vial. Then submit it for
a semiquantitative lab analysis (eg by ICP) for the obvious hard water
components to find out what is actually there. Plenty of labs can
analyse clean drinking water relatively cheaply.
| Quote: | A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping".
|
I am inclined to the view that the reading may well have been real at
the time it was made. The question is how long did it occur for and can
your espresso kit tolerate it happening occasionally.
| Quote: | has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?
|
Why do you suppose the reading was false?
(apart from the assurances of the filter manufacturer)
Try cross posting into sci.chem.analytical and you may pick up some more
tips specific to measurments on potable water.
Regards,
Martin Brown |
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Ernie science forum beginner
Joined: 18 May 2005
Posts: 16
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Posted: Wed May 18, 2005 11:01 am Post subject:
Re: water softening question
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"sprsso" <acritzer@cfl.rr.com> wrote in message
news:1116360370.292963.249450@o13g2000cwo.googlegroups.com...
| Quote: | Hey,
I hope I'm in the right place.
I have a dilemna concerning water hardness testing. I work for a
company that supplies espresso equipment to several large restaurant
chains nationally.
Recently, during a normal repair visit, a technician measured water
exiting the softener at 16gpg. On a visit 2 days later, both the
president of my company and a representative from Ecolab recorded 0gpg.
It is unlikely that the softening cartridge could have been changed
without the knowledge of management. Tests were conducted with Hach
hardness test kits.
A discussion between the pres. and the company that produces our
filters (not the one tested) made mention of false readings occuring as
the ion exchange resin approached saturation with calcium and
magnesium, quality of the resin, and an effect called "dumping". I am
not familiar with these points, but as our resident espresso expert, it
has fallen upon me to find the answers to the following questions:
Can false readings occur at high levels of concentration of minerals
within the softening resin?
How much does the quality of the softening resin impact the
effectiveness of the softener, and could it occlude readings?
Anyone familiar with the term dumping?
If I am not asking in the right place, or the questions are too
amateurish for consideration, I apologize.
If there is someplace where these questions would be more appropriate,
I would appreciate being pointed to it, or any refence locations that
might help.
Thanks in advance....al
|
It seems to me that if the exchange resin is close to used up, and the
sample is taken at high water flow rates, some Mg, and Ca is likely to get
through. On the other hand, if the next sample is taken at very low water
flow rates, or the sample is water that has been sitting in the exchange
cartridge, that sample may be free of Ca & Mg.
The moral of the story is that samples should be taken at flow rates equal
to the fill rate to the espresso machine.
Ernie |
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sprsso science forum beginner
Joined: 17 May 2005
Posts: 5
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Posted: Wed May 18, 2005 3:32 pm Post subject:
Re: water softening question
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Thank you...al |
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